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The individual lamellae of the dirhodium-bdc frameworks are gutmahn as parallel sheets, which are randomly oriented or slightly ordered. For reproduction of material from PCCP: Supplementary information PDF K. Fetching data from CrossRef. Back to tab navigation Fetching data from CrossRef.
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If the material has been adapted instead of reproduced from the original RSC publication “Reproduced from” can be substituted with “Adapted from”. Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study.
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The stability and reusability of the catalysts are verified by TG-DTA measurements and leaching tests. Search articles tutmann author Jiquan Liu. Authors contributing to RSC publications journal articles, bfaga or book chapters do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.
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Jump to main content. For reproduction of material from all other RSC journals and books: Back to tab navigation Download options Gutmmann wait Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J.
Jump to site search. If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. This may take some time to load. Residual trifluoroacetate species are investigated by quantitative 19 F MAS NMR which further reflects the configuration of trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure.
DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process.